Einstein. His Life and Universe

In an article published in the spring of 1906, he argued that relativity conformed to the principle of least action, a foundation of physics that holds that light or any object moving between two points should follow the easiest path.

As usual, Einstein ended by proposing experimental ways to confirm the theory he had just derived. “Perhaps it will prove possible,” he wrote,“to test this theory using bodies whose energy content is variable to a high degree, e.g., salts of radium.”

The formula he used to describe this relationship was also strikingly simple: “If a body emits the energy L in the form of radiation, its mass decreases by L/V 2.” Or, to express the same equation in a different manner:L=mV 2. Einstein used the letter L to represent energy until 1912, when he crossed it out in a manuscript and replaced it with the more common E. He also used V to represent the velocity of light, before changing to the more common c. So, using the letters that soon became standard, Einstein had come up with his memorable equation: E=mc 2

Millikan was wrong to say that Einstein’s formulation of the photo-electric effect had been abandoned. In fact, it was specifically for discovering the law of the photoelectric effect that Einstein would win his only Nobel Prize. With the advent of quantum mechanics in the 1920s, the reality of the photon became a fundamental part of physics.

Einstein’s theory produced a law of the photoelectric effect that was experimentally testable: the energy of emitted electrons would depend on the frequency of the light according to a simple mathematical formula involving Planck’s constant. The formula was subsequently shown to be correct. The physicist who did the crucial experiment was Robert Millikan, who would later head the California Institute of Technology and try to recruit Einstein.

Just before he died, Planck reflected on the fact that he had long recoiled from the implications of his discovery. “My futile attempts to fit the elementary quantum of action somehow into classical theory continued for a number of years and cost me a great deal of effort,” he wrote. “Many of my colleagues saw in this something bordering on a tragedy.” Ironically, similar words would later be used to describe Einstein. He became increasingly “aloof and skeptical” about the quantum discoveries he pioneered, Born said of Einstein. “Many of us regard this as a tragedy.”24

For him, these quanta of energy (which in 1926 were named photons)20 existed even when light was moving through a vacuum.

In addition to the problem of explaining what Planck’s constant was really all about, there was another curiosity about radiation that needed to be explained. It was called the photoelectric effect, and it occurs when light shining on a metal surface causes electrons to be knocked loose and emitted.

Nevertheless, the declaration he made to the Berlin Physical Society in December 1900 was momentous: “We therefore regard—and this is the most essential point of the entire calculation—energy to be composed of a very definite number of equal finite packages.”

In 1900, Planck came up with an equation, partly using what he called “a fortuitous guess,” that described the curve of radiation wavelengths at each temperature. In doing so he accepted that Boltzmann’s statistical methods, which he had resisted, were correct after all. But the equation had an odd feature: it required the use of a constant, which was an unexplained tiny quantity (approximately 6.62607 x 10–34 joule-seconds), that needed to be included for it to come out right. It was soon dubbed Planck’s constant, h, and is now known as one of the fundamental constants of nature.